CobaltMaghrebV1, France, Analysis, bibRecord, 000196

Catalytic behaviour of cobalt exchanged hydroxyapatite in the oxidative dehydrogenation of ethane

Identifieur interne : 000196 ( France/Analysis ); précédent : 000195; suivant : 000197

Catalytic behaviour of cobalt exchanged hydroxyapatite in the oxidative dehydrogenation of ethane

Auteurs : K. Elkabouss [Maroc, France] ; M. Kacimi [Maroc] ; M. Ziyad [Maroc] ; F. Bozon-Verduraz [France]

Source :

Journal de physique. IV [ 1155-4339 ] ; 2005.

RBID : Pascal:05-0362696

Descripteurs français

Pascal (Inist)
- Apatite hydroxylée, Matériau modifié, Echange ion, Cobalt Ion, Métal transition Ion, Calcium Ion, Diffraction RX, Spectrométrie IR, Spectrométrie UV visible, Catalyse hétérogène, Déshydrogénation, Oxydation, Ethane, Hydrocarbure, Alcane, Ethylène.
Wicri :
- topic : Hydrocarbure.

English descriptors

KwdEn :
- Alkane, Calcium Ions, Cobalt Ions, Dehydrogenation, Ethane, Ethylene, Heterogeneous catalysis, Hydrocarbon, Hydroxyapatite, Infrared spectrometry, Ion exchange, Modified material, Oxidation, Transition metal Ions, Ultraviolet visible spectrometry, X ray diffraction.

Abstract

Several samples of exchanged cobalt/calcium (Co²⁺/Ca²⁺) hydroxyapatite were synthesized and characterised by XRD, IR and UV-visible spectroscopy. The level of Co²⁺/Ca²⁺ exchanged was limited to 1.35 wt% of Co and the Co²⁺ ions incorporated in the phosphate matrix were mainly hosted by octahedral sites. The catalytic activity of these materials was measured in the oxidative dehydrogenation of ethane into ethylene in the 450-550°C range. The global conversion and the ethylene yield increase with temperature and depend upon the cobalt content. They reached 35% and 22% at 550°C respectively for a Co wt% of about 1%.

Affiliations:

Links toward previous steps (curation, corpus...)

to stream PascalFrancis, to step Corpus: 000181
to stream PascalFrancis, to step Curation: 000114
to stream PascalFrancis, to step Checkpoint: 000191
to stream Main, to step Merge: 000961
to stream Main, to step Curation: 000950
to stream Main, to step Exploration: 000950
to stream France, to step Extraction: 000196

Links to Exploration step

Pascal:05-0362696

Le document en format XML

<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Catalytic behaviour of cobalt exchanged hydroxyapatite in the oxidative dehydrogenation of ethane</title>
<author><name sortKey="Elkabouss, K" sort="Elkabouss, K" uniqKey="Elkabouss K" first="K." last="Elkabouss">K. Elkabouss</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Physico-Chimie des Matériaux et Catalyse, Faculté des Sciences, Département de Chimie</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<placeName><settlement type="city">Rabat</settlement>
<region nuts="2">Rabat-Salé-Kénitra</region>
</placeName>
</affiliation>
<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Groupe de Chimie des Matériaux Divisés et Catalyse, ITODYS, UMR-CNRS 7086, Université Paris 7-Denis Diderot, 2 place Jussieu</s1>
<s2>75251 Paris</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Île-de-France</region>
<settlement type="city">Paris</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Kacimi, M" sort="Kacimi, M" uniqKey="Kacimi M" first="M." last="Kacimi">M. Kacimi</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Physico-Chimie des Matériaux et Catalyse, Faculté des Sciences, Département de Chimie</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<placeName><settlement type="city">Rabat</settlement>
<region nuts="2">Rabat-Salé-Kénitra</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Ziyad, M" sort="Ziyad, M" uniqKey="Ziyad M" first="M." last="Ziyad">M. Ziyad</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Physico-Chimie des Matériaux et Catalyse, Faculté des Sciences, Département de Chimie</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<placeName><settlement type="city">Rabat</settlement>
<region nuts="2">Rabat-Salé-Kénitra</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Bozon Verduraz, F" sort="Bozon Verduraz, F" uniqKey="Bozon Verduraz F" first="F." last="Bozon-Verduraz">F. Bozon-Verduraz</name>
<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Groupe de Chimie des Matériaux Divisés et Catalyse, ITODYS, UMR-CNRS 7086, Université Paris 7-Denis Diderot, 2 place Jussieu</s1>
<s2>75251 Paris</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Île-de-France</region>
<settlement type="city">Paris</settlement>
</placeName>
</affiliation>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">INIST</idno>
<idno type="inist">05-0362696</idno>
<date when="2005">2005</date>
<idno type="stanalyst">PASCAL 05-0362696 INIST</idno>
<idno type="RBID">Pascal:05-0362696</idno>
<idno type="wicri:Area/PascalFrancis/Corpus">000181</idno>
<idno type="wicri:Area/PascalFrancis/Curation">000114</idno>
<idno type="wicri:Area/PascalFrancis/Checkpoint">000191</idno>
<idno type="wicri:explorRef" wicri:stream="PascalFrancis" wicri:step="Checkpoint">000191</idno>
<idno type="wicri:doubleKey">1155-4339:2005:Elkabouss K:catalytic:behaviour:of</idno>
<idno type="wicri:Area/Main/Merge">000961</idno>
<idno type="wicri:Area/Main/Curation">000950</idno>
<idno type="wicri:Area/Main/Exploration">000950</idno>
<idno type="wicri:Area/France/Extraction">000196</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Catalytic behaviour of cobalt exchanged hydroxyapatite in the oxidative dehydrogenation of ethane</title>
<author><name sortKey="Elkabouss, K" sort="Elkabouss, K" uniqKey="Elkabouss K" first="K." last="Elkabouss">K. Elkabouss</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Physico-Chimie des Matériaux et Catalyse, Faculté des Sciences, Département de Chimie</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<placeName><settlement type="city">Rabat</settlement>
<region nuts="2">Rabat-Salé-Kénitra</region>
</placeName>
</affiliation>
<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Groupe de Chimie des Matériaux Divisés et Catalyse, ITODYS, UMR-CNRS 7086, Université Paris 7-Denis Diderot, 2 place Jussieu</s1>
<s2>75251 Paris</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Île-de-France</region>
<settlement type="city">Paris</settlement>
</placeName>
</affiliation>
</author>
<author><name sortKey="Kacimi, M" sort="Kacimi, M" uniqKey="Kacimi M" first="M." last="Kacimi">M. Kacimi</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Physico-Chimie des Matériaux et Catalyse, Faculté des Sciences, Département de Chimie</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<placeName><settlement type="city">Rabat</settlement>
<region nuts="2">Rabat-Salé-Kénitra</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Ziyad, M" sort="Ziyad, M" uniqKey="Ziyad M" first="M." last="Ziyad">M. Ziyad</name>
<affiliation wicri:level="3"><inist:fA14 i1="01"><s1>Laboratoire de Physico-Chimie des Matériaux et Catalyse, Faculté des Sciences, Département de Chimie</s1>
<s2>Rabat</s2>
<s3>MAR</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
</inist:fA14>
<country>Maroc</country>
<placeName><settlement type="city">Rabat</settlement>
<region nuts="2">Rabat-Salé-Kénitra</region>
</placeName>
</affiliation>
</author>
<author><name sortKey="Bozon Verduraz, F" sort="Bozon Verduraz, F" uniqKey="Bozon Verduraz F" first="F." last="Bozon-Verduraz">F. Bozon-Verduraz</name>
<affiliation wicri:level="3"><inist:fA14 i1="02"><s1>Groupe de Chimie des Matériaux Divisés et Catalyse, ITODYS, UMR-CNRS 7086, Université Paris 7-Denis Diderot, 2 place Jussieu</s1>
<s2>75251 Paris</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>France</country>
<placeName><region type="region" nuts="2">Île-de-France</region>
<settlement type="city">Paris</settlement>
</placeName>
</affiliation>
</author>
</analytic>
<series><title level="j" type="main">Journal de physique. IV</title>
<title level="j" type="abbreviated">J. phys., IV</title>
<idno type="ISSN">1155-4339</idno>
<imprint><date when="2005">2005</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><title level="j" type="main">Journal de physique. IV</title>
<title level="j" type="abbreviated">J. phys., IV</title>
<idno type="ISSN">1155-4339</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Alkane</term>
<term>Calcium Ions</term>
<term>Cobalt Ions</term>
<term>Dehydrogenation</term>
<term>Ethane</term>
<term>Ethylene</term>
<term>Heterogeneous catalysis</term>
<term>Hydrocarbon</term>
<term>Hydroxyapatite</term>
<term>Infrared spectrometry</term>
<term>Ion exchange</term>
<term>Modified material</term>
<term>Oxidation</term>
<term>Transition metal Ions</term>
<term>Ultraviolet visible spectrometry</term>
<term>X ray diffraction</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Apatite hydroxylée</term>
<term>Matériau modifié</term>
<term>Echange ion</term>
<term>Cobalt Ion</term>
<term>Métal transition Ion</term>
<term>Calcium Ion</term>
<term>Diffraction RX</term>
<term>Spectrométrie IR</term>
<term>Spectrométrie UV visible</term>
<term>Catalyse hétérogène</term>
<term>Déshydrogénation</term>
<term>Oxydation</term>
<term>Ethane</term>
<term>Hydrocarbure</term>
<term>Alcane</term>
<term>Ethylène</term>
</keywords>
<keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Hydrocarbure</term>
</keywords>
</textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Several samples of exchanged cobalt/calcium (Co<sup>2+</sup>
/Ca<sup>2+</sup>
) hydroxyapatite were synthesized and characterised by XRD, IR and UV-visible spectroscopy. The level of Co<sup>2+</sup>
/Ca<sup>2+</sup>
 exchanged was limited to 1.35 wt% of Co and the Co<sup>2+</sup>
 ions incorporated in the phosphate matrix were mainly hosted by octahedral sites. The catalytic activity of these materials was measured in the oxidative dehydrogenation of ethane into ethylene in the 450-550°C range. The global conversion and the ethylene yield increase with temperature and depend upon the cobalt content. They reached 35% and 22% at 550°C respectively for a Co wt% of about 1%.</div>
</front>
</TEI>
<affiliations><list><country><li>France</li>
<li>Maroc</li>
</country>
<region><li>Rabat-Salé-Kénitra</li>
<li>Île-de-France</li>
</region>
<settlement><li>Paris</li>
<li>Rabat</li>
</settlement>
</list>
<tree><country name="Maroc"><region name="Rabat-Salé-Kénitra"><name sortKey="Elkabouss, K" sort="Elkabouss, K" uniqKey="Elkabouss K" first="K." last="Elkabouss">K. Elkabouss</name>
</region>
<name sortKey="Kacimi, M" sort="Kacimi, M" uniqKey="Kacimi M" first="M." last="Kacimi">M. Kacimi</name>
<name sortKey="Ziyad, M" sort="Ziyad, M" uniqKey="Ziyad M" first="M." last="Ziyad">M. Ziyad</name>
</country>
<country name="France"><region name="Île-de-France"><name sortKey="Elkabouss, K" sort="Elkabouss, K" uniqKey="Elkabouss K" first="K." last="Elkabouss">K. Elkabouss</name>
</region>
<name sortKey="Bozon Verduraz, F" sort="Bozon Verduraz, F" uniqKey="Bozon Verduraz F" first="F." last="Bozon-Verduraz">F. Bozon-Verduraz</name>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/CobaltMaghrebV1/Data/France/Analysis

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000196 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/France/Analysis/biblio.hfd -nk 000196 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/Terre
   |area=    CobaltMaghrebV1
   |flux=    France
   |étape=   Analysis
   |type=    RBID
   |clé=     Pascal:05-0362696
   |texte=   Catalytic behaviour of cobalt exchanged hydroxyapatite in the oxidative dehydrogenation of ethane
}}

This area was generated with Dilib version V0.6.32.
Data generation: Tue Nov 14 12:56:51 2017. Site generation: Mon Feb 12 07:59:49 2024

	Serveur d'exploration sur le cobalt au Maghreb
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration sur le cobalt au Maghreb

Catalytic behaviour of cobalt exchanged hydroxyapatite in the oxidative dehydrogenation of ethane

Catalytic behaviour of cobalt exchanged hydroxyapatite in the oxidative dehydrogenation of ethane

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri